MMaterialsgateNEWS 2018/01/30

X-Ray Experiments Suggest High Tunability of 2-D Material

Scientists at Berkeley Lab use a new platform, called MAESTRO, to see microscale details in monolayer material’s electronic structure

To see what is driving the exotic behavior in some atomically thin – or 2-D – materials, and find out what happens when they are stacked like Lego bricks in different combinations with other ultrathin materials, scientists want to observe their properties at the smallest possible scales.

Enter MAESTRO, a next-generation platform for X-ray experiments at the Advanced Light Source (ALS) at the Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab), that is providing new microscale views of this weird 2-D world.

In a study published Jan. 22 in the journal Nature Physics, researchers zeroed in on signatures of exotic behavior of electrons in a 2-D material with microscale resolution.

The new insights gleaned from these experiments show that the properties of the 2-D semiconductor material they studied, called tungsten disulfide (WS2), may be highly tunable, with possible applications for electronics and other forms of information storage, processing, and transfer.

Those applications could include next-gen devices spawned from emerging fields of research like spintronics, excitonics and valleytronics. In these fields, researchers seek to manipulate properties like momentum and energy levels in a material’s electrons and counterpart particles to more efficiently carry and store information – analogous to the flipping of ones and zeroes in conventional computer memory.

Spintronics, for example, relies on the control of an inherent property of electrons known as spin, rather than their charge; excitonics could multiply charge carriers in devices to improve efficiency in solar panels and LED lighting; and valleytronics would use separations in a material’s electronic structures as distinct pockets or “valleys” for storing information.

The signal they measured using MAESTRO (Microscopic and Electronic Structure Observatory) revealed a substantially increased splitting between two energy levels, or “bands,” associated with the material’s electronic structure. This increased splitting bodes well for its potential use in spintronics devices.

WS2 is already known to interact strongly with light, too. The new findings, coupled with its previously known properties, make it a promising candidate for optoelectronics, in which electronics can be used to control the release of light, and vice versa.

“These properties could be very exciting technologically,” said Chris Jozwiak, an ALS staff scientist who co-led the study. The latest research “in principle shows the ability to change these key properties with applied electric fields in a device.”

He added, “The ability to engineer the features of the electronic structures of this and other materials could be very useful in making some of these possibilities come true. We are right now at the brink of being able to study a huge variety of materials, and to measure their electronic behavior and study how these effects develop at even smaller scales.”

The study also suggest that trions, which are exotic three-particle combinations of electrons and excitons (bound pairs of electrons and their oppositely charged counterpart “holes”), could explain the effects they measured in the 2-D material. Holes and electrons both serve as charge carriers in semiconductors found in popular electronic devices.

Researchers used a form of ARPES (angle-resolved photoemission spectroscopy) at the MAESTRO beamline to kick away electrons from samples with X-rays and learn about the samples’ electronic structure from the ejected electrons’ direction and energy. The technique can resolve how the electrons in the material interact with each other.

“There are very few direct observations of a particle interacting with two or more other particles,” said Eli Rotenberg, a senior staff scientist at ALS who conceptualized MAESTRO more than a decade ago. It was built with the goal to directly observe such “many-body” interactions in detail not possible before, he said. “This is what we were going for when we built the MAESTRO beamline.”

MAESTRO, which opened to scientists in 2016, also features several stations that allow researchers to fabricate and manipulate samples for X-ray studies while maintaining pristine conditions that protect them from contamination. MAESTRO is one among dozens of X-ray beamlines at the ALS that are specialized for samples ranging from proteins and vaccines to batteries and meteorites.

In addition to MAESTRO’s precise measurements, the careful preparation of the tungsten disfulfide flakes in sufficient size for study, and their transfer to a base material (substrate) that didn’t impede their electronic properties or obstruct the X-ray measurements were also vital in the success of the latest study, Jozwiak noted.

Jyoti Katoch, the study’s lead author and a research scientist at The Ohio State University, said, “Two-dimensional materials are extremely sensitive to their surroundings, so it’s imperative to fully understand the role of any outside disturbances that affect their properties.”

Katoch worked with Roland Kawakami, a physics professor at Ohio State, in preparing the samples and designing the experiment. They coupled samples of WS2 to boron nitride, which provided a stable, non-interacting platform that was crucial for the X-ray measurements. Then they used a metal as an “external knob” to modify the properties of the WS2.

“This study enables two critical breakthroughs: it provides a clear fundamental understanding of how to remove outside effects when measuring the intrinsic properties of 2-D materials, and it allows us to tune the properties of 2-D materials by simply modifying their environment.”

Søren Ulstrup, an assistant professor at Aarhus University who had worked on the WS2 MAESTRO experiments as a postdoctoral researcher, added, “Seeing the intrinsic electronic properties of the WS2 samples was an important step, but perhaps the biggest surprise of this study emerged when we started to increase the number of electrons in the system – a process called doping.

“This lead to the dramatic change of the splitting in the band structure of WS2,” he said, which suggests the presence of trions.

MAESTRO can handle very small sample sizes, on the order of tens of microns, noted Rotenberg, which is also a key in studying this and other 2-D materials. “There’s a big push to resolve materials’ properties on smaller and smaller scales,” he said, to better understand the fundamental properties of 2-D materials, and scientists are now working to push MAESTRO’s capabilities to study even smaller features – down to the nanoscale.

There is accelerating R&D into stacking 2-D layers to tailor their properties for specialized applications, Jozwiak said, and MAESTRO is well-suited to measuring the electronic properties of these stacked materials, too.

“We can see a very explicit impact on properties by combining two materials, and we can see how these effects change when we change which materials we’re combining,” he said.

“There is an endless array of possibilities in this world of ‘2-D Legos,’ and now we have another window into these fascinating behaviors.”

Source: DOE/Lawrence Berkeley National Laboratory – 26.01.2018.

Investigated and edited by:

Dr.-Ing. Christoph Konetschny, Inhaber und Gründer von Materialsgate
Büro für Material- und Technologieberatung
The investigation and editing of this document was performed with best care and attention.
For the accuracy, validity, availability and applicability of the given information, we take no liability.
Please discuss the suitability concerning your specific application with the experts of the named company or organization.

You want additional material or technology investigations concerning this subject?

Materialsgate is leading in material consulting and material investigation.
Feel free to use our established consulting services

MMore on this topic

Rice University study shows 2-D layers of boron nitride could aid strength, toughness and thermal conductivity of ceramics

A little hBN in ceramics could give them outstanding properties, according to a Rice University scientist. Rouzbeh Shahsavari, an assistant professor of civil and environmental engineering, suggested the incorporation of ultrathin hexagonal boron nitride (hBN) sheets between layers of calcium-silicates would make an interesting bilayer crystal with multifunctional properties. These could be suitable for construction and refractory materials and applications in the nuclear industry, oil and gas, aerospace and other areas that require high-performance composites. Combining the materials would make a ceramic that’s not only tough and durable but resistant to heat and radiation. By Shahsavari’s... more read more

Subnanometer-scale channels in 2-D materials could point toward future electronics and solar cells.

“Two-dimensional materials” — materials deposited in layers that are only a few atoms thick — are promising for both high-performance electronics and flexible, transparent electronics that could be layered onto physical surfaces to make computing ubiquitous. The best-known 2-D material is graphene, which is a form of carbon, but recently researchers have been investigating other 2-D materials, such as molybdenum disulfide, which have their own, distinct advantages. Producing useful electronics, however, requires integrating multiple 2-D materials in the same plane, which is a tough challenge. In 2015, researchers at King Abdullah University in Saudi Arabia developed a technique... more read more

IBS physicists found that to shed light on the cracking of MoS2, we must go beyond the theory used so far

Cracks sank the 'unsinkable' Titanic; decrease the performance of touchscreens and erode teeth. We are familiar with cracks in big or small three-dimensional (3D) objects, but how do thin two-dimensional (2D) materials crack? 2D materials, like molybdenum disulfide (MoS2), have emerged as an important asset for future electronic and photoelectric devices. However, the mechanical properties of 2D materials are expected to differ greatly from 3D materials. Scientists at the Center for Integrated Nanostructure Physics (CINAP), within the Institute for Basic Science (IBS) published, on Nature Communications, the first observation of 2D MoS2 cracking at the atomic level. This study is... more read more

Two-dimensional (2D) nanomaterials have been made by dissolving layered materials in liquids, according to new UCL-led research. The liquids can be used to apply the 2D nanomaterials over large areas and at low costs, enabling a variety of important future applications.

2D nanomaterials, such as graphene, have the potential to revolutionise technology through their remarkable physical properties, but their translation into real world applications has been limited due to the challenges of making and manipulating 2D nanomaterials on an industrial scale. The new approach, published today in Nature Chemistry, produced single layers of many 2D nanomaterials in a scalable way. The researchers used the method on a wide variety of materials, including those with semiconductor and thermoelectric properties, to create 2D materials that could be used in solar cells or for turning wasted heat energy into electrical energy, for example. "2D nanomaterials have... more read more

MaterialsgateNEWSLETTER

Partner of the Week

Search in MaterialsgateNEWS

MaterialsgateFAIR:
LET YOURSELF BE INSPIRED