The key to the finding, published in Science, involves a method to measure intrinsic conducting properties of ferroelectric materials, which for decades have held tremendous promise but have eluded experimental proof. Now, however, ORNL Wigner Fellow Peter Maksymovych and co-authors Stephen Jesse, Art Baddorf and Sergei Kalinin at the Center for Nanophase Materials Sciences believe they may be on a path that will see barriers tumble.

"For years, the challenge has been to develop a nanoscale material that can act as a switch to store binary information," Maksymovych said. "We are excited by our discovery and the prospect of finally being able to exploit the long-conjectured bi-stable electrical conductivity of ferroelectric materials.

"Harnessing this functionality will ultimately enable smart and ultra-dense memory technology."

In the paper, the authors have demonstrated for the first time a giant intrinsic electroresistance in conventional ferroelectric films, where flipping of the spontaneous polarization increased conductance by up to 50,000 percent. Ferroelectric materials can retain their electrostatic polarization and are used for piezoactuators, memory devices and RFID (radio-frequency identification) cards.

"It is as if we open a tiny door in the polar surface for electrons to enter," Maksymovych said. "The size of this door is less than one-millionth of an inch, and it is very likely taking only one-billionth of a second to open."

As the paper illustrates, the key distinction of ferroelectric memory switches is that they can be tuned through thermodynamic properties of ferroelectrics.

"Among other benefits, we can use the tunability to minimize the power needed for recording and reading information and read-write voltages, a key requirement for any viable memory technology," Kalinin said.

Numerous previous works have demonstrated defect-mediated memory, but defects cannot easily be predicted, controlled, analyzed or reduced in size, Maksymovych said. Ferroelectric switching, however, surpasses all of these limitations and will offer unprecedented functionality. The authors believe that using phase transitions such as ferroelectric switching to implement memory and computing is the real fundamental distinction of future information technologies.

Making this research possible is a one-of-a-kind instrument that can simultaneously measure conducting and polar properties of oxide materials with nanometer-scale spatial resolution under a controlled vacuum environment. The instrument was developed and built by Baddorf and colleagues at the Center for Nanophase Materials Sciences. The materials used for this study were grown and provided by collaborators at the University of California at Berkeley.

A link to the paper, "Polarization control of electron tunneling into ferroelectric surfaces," is available here: http://www.sciencemag.org/cgi/content/abstract/324/5933/1421; Vol. 324, 2009, page 1421. This research was funded by the Office of Basic Energy Sciences within the Department of Energy's Office of Science. UT-Battelle manages Oak Ridge National Laboratory for DOE.

The Center for Nanophase Materials Sciences at Oak Ridge National Laboratory is one of the five DOE Nanoscale Science Research Centers, premier national user facilities for interdisciplinary research at the nanoscale. Together the centers comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The centers are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge, Sandia and Los Alamos national laboratories.

Source: Oak Ridge National Laboratory - June 16, 2009.